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The gases a rocky planet releases depend on how oxidised its mantle is. 🌋 That matters for biosignatures: you can't say a gas is unusual without knowing what a lifeless planet would produce. And you can't measure mantle chemistry directly from ten parsecs away.

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So we tested whether it can be measured indirectly. Atmospheres for six mantle oxidation states, twelve orders of magnitude in oxygen fugacity, then a simulation of what LIFE would see for Earth-sized planets at 1 AU around a Sun-like star at 10 parsecs.

The six states can be told apart. Carbon dioxide dominates the oxidised cases, ammonia the reduced ones, and methane peaks in the middle, which is what separates the two most oxidised cases. Plot: retrieved abundance of each gas, black bars for the true values.

Reduced atmospheres are harder to retrieve than oxidised ones, because their spectra are flatter. In the spectra on the first post: top row reduced, bottom oxidised, red the input model, blue the retrieved range, grey the noise. Hydrogen and nitrogen were not useful.